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Free Books / Science / Distillation Principles And Processes / | ![]() |
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List Of Known Azeotropic Mixtures. Part 2 |
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This section is from the book "Distillation Principles And Processes", by Sydney Young. Also available from Amazon: Distillation Principles And Processes.
|
Substances in mixture. |
Percentage of A. by weight in mixture. |
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|
Observer. |
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|
A. |
B. |
A. |
B. |
Az mix ture. |
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|
Water |
Nitric acid |
100.0 |
86.0 |
120.5 |
32 |
R. |
|
Water |
Hydrochloric acid |
100.0 |
-84 |
110 |
79.76 |
R. |
|
Water |
Hydrobromic acid |
100.0 |
-73 |
126 |
52.5 |
R |
|
Water |
Hydriodic acid |
100.0 |
-34 |
127 |
43 |
R. |
|
Water |
Hydrofluoric acid |
100.0 |
19.4 |
120 |
63 |
R. |
|
Water |
Formic acid |
100.0 |
99.9 |
107.1 |
22.5 |
R. |
|
Water |
Formic acid |
100.0 |
100.75 |
107.3 |
22.5 |
L. |
|
Water |
Perchloric acid |
100.0 |
110.0 |
203 |
28.4 |
R. |
|
Formic acid |
Diethyl ketone |
100.75 |
102.2 |
105.4 |
33 |
L. |
|
Formic acid |
Methyl propyl ketone |
100.75 |
102.25 |
105.3 |
32 |
L. |
|
Propionic acid |
Acetylacetone |
140.7 |
138 |
144 |
70 |
L. |
|
Hydrochloric acid |
Methyl ether |
- 84 |
-23.65 |
-1.5 |
60 |
F., L. |
|
Formic acid |
Pyridine |
100.7 |
116.7 |
149 |
18 |
Ga., An., Z„ L. |
|
Formic acid |
Picoline, a |
100.7 |
134 |
158 |
25 |
Ga., L. |
|
Acetic acid |
Pyridine |
118.5 |
115.5 |
139.7 |
35 |
Ga., An., L. |
|
Acetic acid |
Picoline, a |
118.5 |
134 |
146 |
40 |
Ga., Z. |
|
Propionic acid |
Pyridine |
140.7 |
116.7 |
150.151 |
31.5 |
Ga., An., L. |
|
Cyclo-hexanol |
181.5 |
160.65 |
182.45 |
90.5 |
L. |
|
|
Phenol |
Sec. octyl alcohol |
181.5 |
178.5 |
184.65 |
50 |
L. |
|
Phenol |
Glycol |
181.5 |
197.4 |
199 |
22 |
L. |
|
Cresol, p. |
Glycol |
201.8 |
197.4 |
203 |
68 |
L. |
|
Cresol, p. |
Benzyl alcohol |
201.8 |
205.5 |
207.0 |
38 |
L. |
|
Phenol |
Benzaldehyde |
181.5 |
179.2 |
185.6 |
51 |
L. |
|
Phenol |
Aniline |
181.5 |
184.35 |
186.22 |
42 |
L. |
|
Cresol, o. |
Dimethyl aniline |
190.8 |
194.05 |
195.6 |
<30 |
L. |
|
Cresol, o. |
Methyl aniline |
190.8 |
196.1 |
196.7 |
10 |
L. |
|
Cresol, p. |
Toluidine, p. |
201.8 |
200.3 |
204.35 |
57 |
L. |
|
Cresol, p. |
Toluidine, o. |
201.8 |
200.7 |
204.5 |
53 |
L. |
|
Cresol, p. |
Ethyl aniline |
201.8 |
206.05 |
207.2 |
<20 |
L. |
|
Cresol, o. |
Acetophenone |
190.8 |
202 |
203.7 |
22 |
L. |
|
Cresol, p. |
Fenchone |
201.8 |
193 |
205 |
72 |
L. |
|
Cresol, p. |
Acetophenone |
201.8 |
202 |
208.45 |
50 |
L. |
|
Cresol, p. |
Camphor |
201.8 |
208.9 |
213.15 |
30 |
L. |
|
Cresol, m. |
Acetophenone |
202.8 |
202 |
209 |
52 |
L. |
|
Cresol, m. |
Camphor |
202.8 |
208.9 |
213.5 |
35 |
L. |
|
Phenol |
Isoamyl butyrate |
181.5 |
178.6 |
185.6 |
61 |
L. |
|
Phenol |
Isobutyl lactate |
181.5 |
182.15 |
189.05 |
46 |
L. |
|
Phenol |
Ethyl oxalate |
181.5 |
185 0 |
189.1 |
43 |
L. |
|
Cresol, o. |
Ethyl oxalate |
190.8 |
1850 |
193.9 |
67 |
L. |
|
Cresol, o. |
Methyl benzoate |
190.8 |
199.55 |
200.8 |
30 |
L. |
|
Cresol, p. |
Methyl benzoate |
201.8 |
199.55 |
204.7 |
85 |
L. |
|
Cresol, p. |
Isoamyl lactate |
201.8 |
202.4 |
207.25 |
48 |
L. |
|
Cresol, m. |
Methyl benzoate |
202.8 |
199.55 |
205.6 |
88 |
L. |
|
Cresol, m. |
Isoamyl lactate |
202.8 |
202.4 |
207.6 |
50 |
L. |
|
56.4 |
61.2 |
64.7 |
20 |
Ry., Th., L., Ty., Y. |
||
|
Diethyl ketone |
Dichloro-bromo-methane |
102.2 |
90.2 |
103.0 |
64 |
L. |
|
Camphor |
Benzal chloride |
208.9 |
205.1 |
209.7 |
75 |
L. |
|
Chloroform |
Ethyl formate |
61.2 |
54.15 |
62.7 |
87 |
L. |
|
Chloroform |
Methyl acetate |
61.2 |
57.05 |
64.8 |
77 |
Ry., L. |
|
Pentachlorethane |
Mesitylene |
161.95 |
164.0 |
166 |
44 |
L. |
|
Hydrogen bromide |
Hydrogen sulphide |
. . . |
. . . |
-70 |
61 |
S. &B. |
 
Continue to:
liquids, distillation, vapour, boiling point, composition, still-head, mixtures, compositions, sublimation, alcohol, acetone, water, purification, pressure, tar, raw material, essential oils
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