Alkali is the commercial and industrial name for a strong base, such as caustic soda (NaOH), caustic potash (KOH), and ammonium hydroxide (NH 4OH). An alkali is opposite to an acid in character and turns red litmus paper blue. When a limited amount of acid is added to an excess of alkali, only part of the OH (hydroxide radical) is replaced by a negative element or radical, and a basic salt is formed.

To illustrate: If excess iron (ferric) hydroxide and a limited amount of hydrochloric acid are mixed the result is:

Fe(OH)3 + HCl = FeCl (OH)2 + H 2O or

149 The Formation Of Alkalies 68

+

HCl

=

149 The Formation Of Alkalies 69

+

H1O

Ferric Hydroxide

Hydrochloric Acid

Basic Ferric Chloride

Water

The most important of the alkalies in caustic soda which is made from soda ash by adding milk of lime (calcium hydroxide) to the solution.

Na2CO3

+

Ca(OH)2

=

CaCO3

+

2NaOH

Soda Ash

Milk of Lime

Calcium Carbonate

Caustic Soda

The calcium carbonate separates as a sediment.