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List Of Known Azeotropic Mixtures |
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List Of Known Azeotropic Mixtures |
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This section is from the book "Distillation Principles And Processes", by Sydney Young. Also available from Amazon: Distillation Principles And Processes.
|
Substances in mixture. |
Percentage of A. by weight in mixture. |
|||||
|
Observer, |
||||||
|
A. |
B. |
A. |
B. |
Az. mix-ture. |
||
|
O |
O |
O |
||||
|
Water |
Ethyl alcohol |
100 0 |
78.3 |
78.15 |
4.43 |
N. & W., Y. & F., W., Vr., M. |
|
Water |
Isopropyl alcohol |
100 0 |
82.44 |
80.37 |
12.10 |
Y. &F. |
|
Water |
Tertiary butyl alcohol |
100.0 |
82.55 |
79.91 |
11.76 |
Y. & F. |
|
Water |
n. Propyl alcohol |
1000 |
97.20 |
87.72 |
28.31 |
Ch., K., Y. & F., Vr. D., w'& A., L. |
|
Water |
Allyl alcohol |
1000 |
96.95 |
88.0 |
28.0 |
|
|
Isopentane |
64.7 |
27.95 |
24.5 |
4 |
L. |
|
|
Methyl alcohol |
Trimethylethylene |
64.7 |
37.15 |
31.75 |
7 |
L. |
|
Methyl alcohol |
Diallyl |
64.7 |
60.2 |
47.05 |
22.5 |
L. |
|
Methyl alcohol |
n. Hexane |
64.7 |
68.95 |
50.0 |
26.9 |
Ry., Y, L. |
|
Methyl alcohol |
Benzene |
64.7 |
80.2 |
58.34 |
39.55 |
Ry., Y. & F. |
|
Methyl alcohol |
Cyclo-hexane |
64.7 |
80.75 |
54.2 |
37.2 |
L. |
|
Methyl alcohol |
Cyclo-hexadiene, 1.3 |
64.7 |
80.8 |
56.38 |
38.8 |
L. |
|
Methyl alcohol |
Cyclo-hexene |
64.7 |
82.75 |
55.9 |
40 |
L. |
|
Methyl alcohol |
n. Heptane |
64.7 |
98.45 |
60.5 |
62 |
L. |
|
Methyl alcohol |
Methyl cyclo-hexane |
64.7 |
101.8 |
60 |
70 |
L. |
|
Ethyl alcohol |
Diallyl |
78.3 |
60.2 |
53.5 |
13 |
L. |
|
Ethyl alcohol |
n. Hexane |
78.3 |
68.95 |
58.65 |
21 |
Y. |
|
Ethyl alcohol |
Benzene |
78.3 |
80.2 |
68.24 |
32.37 |
Th., Ry., M., Y. &F. |
|
Ethyl alcohol |
Cyclo-hexane |
78.3 |
80.75 |
64.9 |
30.5 |
L. |
|
Ethyl alcohol |
Cyclo-hexadiene, 1.3 |
78.3 |
80.8 |
66.7 |
34 |
L. |
|
Ethyl alcohol |
Cyclo-hexene |
78.3 |
82.75 |
66.7 |
35 |
L. |
|
Ethyl alcohol |
Methyl cyclo-hexane |
78.3 |
101.8 |
73 |
53 |
L. |
|
Ethyl alcohol |
Toluene |
78.3 |
110.6 |
76.7 |
68 |
Y., L. |
|
Isopropyl alcohol |
n. Hexane |
82.45 |
68.95 |
61 |
22 |
L. |
|
Isopropyl alcohol |
Benzene |
82.45 |
80.2 |
71.92 |
33.3 |
Ry., Y. & F. |
|
Isopropyl alcohol |
Cyclo-hexane |
82.45 |
80.75 |
68.6 |
33 |
L. |
|
Isopropyl alcohol |
Cyclo-hexadiene, 1.3 |
82.45 |
80.8 |
70.4 |
36 |
L. |
|
Isopropyl alcohol |
Cyclo-hexene |
82.45 |
82.75 |
71 |
36 |
L. |
|
Isopropyl alcohol |
Toluene |
82.45 |
110.6 |
80.6 |
69 |
Y.,L. |
|
Tert. butyl alcohol |
Benzene |
82.55 |
80.2 |
73.95 |
36.6 |
Y. &F. |
|
Tert. butyl alcohol |
Cyclo-hexane |
82.55 |
80.75 |
71.8 |
37 |
L. |
|
Tert. butyl alcohol |
Cyclo-hexadiene, 1.3 |
82.55 |
80.8 |
73.4 |
38.5 |
L. |
|
Tert. butyl alcohol |
Cyclo-hexene |
82.55 |
82.75 |
73.7 |
38 |
L. |
|
n. Propyl alcohol |
n. Hexane |
97.2 |
68.95 |
65.65 |
4 |
Y., L. |
|
n. Propyl alcohol |
Benzene |
97.2 |
80.2 |
77.12 |
16.9 |
Ry., Y, |
|
n. Propyl alcohol |
Cyclo-hexane |
97.2 |
80.75 |
74.3 |
20 |
L. |
|
n. Propyl alcohol |
Cyclo-hexadiene, 1.3 |
97.2 |
80.8 |
76.1 |
21 |
L. |
|
n. Propyl alcohol |
Cyclo-hexene |
97.2 |
82.75 |
76.6 |
21.6 |
L. |
|
n. Propyl alcohol |
Toluene |
97.2 |
110.6 |
92.6 |
49 |
Ry., L. |
|
n. Propyl alcohol |
n. Octane |
97.2 |
125.8 |
95 |
74 |
L. |
|
Allyl alcohol |
Benzene |
97.05 |
80.2 |
76.75 |
17.36 |
L., W. & A. |
|
Allyl alcohol |
Cyclo-hexane |
96.95 |
80.75 |
74 |
20 |
L. |
|
Allyl alcohol |
Cyclo-hexadiene, 1.3 |
96.95 |
80.8 |
75.9 |
21 |
L. |
|
Allyl alcohol |
Cyclo-hexene |
96.95 |
82.75 |
76.3 |
21.7 |
L. |
|
Allyl alcohol |
Toluene |
96.95 |
110.6 |
92.4 |
50 |
Ry., L. |
|
Isobutyl alcohol |
n. Hexane |
108.05 |
68.95 |
68.1 |
2 |
Y., L. |
|
Isobutyl alcohol |
Benzene |
108.05 |
80.2 |
79.84 |
9.3 |
' Y. |
|
Isobutyl alcohol |
Cyclo-hexane |
108.0 |
80.75 |
78.1 |
14 |
L. |
|
Isobutyl alcohol |
Cyclo-hexadiene, 1.3 |
108.0 |
80.8 |
79.35 |
12 |
L. |
|
Isobutyl alcohol |
Cyclo-hexene |
108.0 |
82.75 |
80.5 |
14.2 |
L. |
|
Isobutyl alcohol |
Toluene |
108.0 |
110.6 |
101.15 |
44.5 |
Ry., L. |
|
Isobutyl alcohol |
Ethyl benzene |
108.0 |
13615 |
107.4 |
80 |
L. |
|
n. Butyl alcohol |
Cyclo-hexane |
116.9 |
80.75 |
79.8 |
10 |
L. |
|
n. Butyl alcohol |
Toluene |
116.9 |
110.6 |
105.5 |
32 |
L. |
|
Isoamyl alcohol |
Ethyl benzene |
131.8 |
136.15 |
125.9 |
49 |
L. |
|
Isoamyl alcohol |
Xylene, p. |
131.8 |
138.2 |
126.8 |
51 |
Ry., L. |
|
Iasomal alcohol |
Xylene, m. |
131.8 |
139.0 |
127.0 |
53 |
Ry., L. |
|
Isomyl alcohol |
Xylene, o. |
131.8 |
142.6 |
128.0 |
60 |
Ry., L. |
|
Isomylhexanol |
Pinene |
160.65 |
155.8 |
149.9 |
35.5 |
L. |
|
Isoamyl-hexanol |
Mesitylene |
160.65 |
164.0 |
156.3 |
50 |
L. |
|
Isoamyl-hexanol |
Cymene |
160.65 |
175.3 |
159 |
71 |
L. |
|
cyclo-hexanol |
Carvene |
160.65 |
177.8 |
159.25 |
73.5 |
L |
|
Octyl alcohol |
Carvene |
178.7 |
177.8 |
174.4 |
35 |
L |
|
yl alcohol |
Carvene |
205.5 |
177.8 |
176.25 |
11 |
L. |
|
Substances in mixture. |
Boiling points. |
Percentage of A. by weight in mixture. |
Observer. |
|||
|
A. |
B. |
A. |
B. |
A.z. mix-lure. |
||
|
0 |
o |
o |
||||
|
Benzyl alcohol |
Naphthalene |
205.5 |
218.1 |
204.3 |
60 |
L. |
|
Methyl alcohol |
Ethyl bromide |
64.7 |
38.4 |
34.95 |
4.5 |
Ry. L. |
|
Methyl alcohol |
Methyl iodide |
64.7 |
44.5 |
39.0 |
7.2 |
B., L. |
|
Methyl alcohol |
Ethylidene chloride |
64.7 |
57.3 |
49.05 |
11.5 |
L. |
|
Methyl alcohol |
64.7 |
61.2 |
53.5 |
12.5 |
By., Ry., P., Ty., Ti. |
|
|
Methyl alcohol |
Isobutyl chloride |
64.7 |
68.9 |
53.05 |
23 |
L. |
|
Methyl alcohol |
Propyl bromide |
64.7 |
71.0 |
54.1 |
20.2 |
L. |
|
Methyl alcohol |
Ethyl iodide |
64.7 |
72.3 |
54.7 |
18.5 |
Ry., L. |
|
Methyl alcohol |
Tert. butyl bromide |
64.7 |
73.3 |
55.6 |
24 |
L. |
|
Methyl alcohol |
Carbon tetrachloride |
64.7 |
76.75 |
55.7 |
20.56 |
T., Y. |
|
Methyl alcohol |
Trichlorethylene |
64.7 |
86.95 |
60.2 |
36 |
L. |
|
Methyl alcohol |
Dichloro-bromo-methane |
64.7 |
90.2 |
63.8 |
40 |
L. |
|
Methyl alcohol |
Isobutyl bromide |
64.7 |
91.6 |
61.4 |
42 |
L. |
|
Methyl alcohol |
Propyl iodide |
64.7 |
102.4 |
63.5 |
61 |
L. |
|
Ethyl alcohol |
Ethyl bromide |
78.3 |
38.4 |
37.6 |
3 |
Ry., L, |
|
Ethyl alcohol |
Propyl chloride |
78.3 |
46.6 |
44.9 |
5.5 |
L. |
|
Ethyl alcohol |
Acetylene dichloride, tr. |
78.3 |
48.35 |
46.5 |
6 |
Cv. |
|
Ethyl alcohol |
Dibromopropylene, a, cis. |
78.3 |
57.8 |
56.4 |
9 |
Cv. |
|
Ethyl alcohol |
Acetylene dicoloride, cis. |
78.3 |
60.25 |
57.7 |
9-8 |
Cv. |
|
Ethyl alcohol |
Chloroform |
78.3 |
61.16 |
59.4 |
7.0 |
Th., Ry., L., W. |
|
Ethyl alcohol |
Isobutyl chloride |
78.3 |
68.9 |
61.45 |
16.3 |
L. |
|
Ethyl alcohol |
Propyl bromide |
78.3 |
71.0 |
63 |
17 |
B., L. |
|
Ethyl alcohol |
Ethyl iodide |
78.3 |
72.3 |
63 |
13 |
Ry., J. & G., I. |
|
Ethyl alcohol |
Tert. butyl bromide |
78.3 |
73.3 |
63.8 |
15 |
L. |
|
Ethyl alcohol |
Carbon tetrachloride |
78.3 |
76.7 |
64.95 |
15.85 |
Y., By., Sch., Ty., Bi., L. |
|
Ethyl alcohol |
Trichlorethylene |
78.3 |
86.95 |
70.9 |
27 |
L. |
|
Ethyl alcohol |
Dichloro-bromo-methane |
78.3 |
90.2 |
75.05 |
28 . |
L. |
|
Ethyl alcohol |
Isobutyl bromide |
78.3 |
91.6 |
72.7 |
38 |
B., L. |
|
Ethyl alcohol |
Allyl iodide |
78.3 |
102 |
75.6 |
41 |
L. |
|
Ethyl alcohol |
Isobutyl iodide |
78.3 |
120 |
77.65 |
70 |
Ry., L. |
|
Ethyl alcohol |
Isoamyl bromide |
78.3 |
120.2 |
77.6 |
71.5 |
B., L. |
|
Ethyl alcohol |
Tetrachlorethylene |
78.3 |
120.8 |
77.95 |
81 |
L. |
|
Isopropyl alcohol |
Isobutyl chloride |
82.45 |
68.9 |
63.8 |
17 |
L. |
|
Isopropyl alcohol |
Ethyl iodide |
82.45 |
72.3 |
65.8 |
>15 |
Ry., L. |
|
Isopropyl alcohol |
Isobutyl iodide |
82.45 |
120.0 |
81.8 |
76 |
Ry., L. |
|
Tert. butyl alcohol |
Carbon tetrachloride |
82.55 |
76.75 |
69.5 |
17 |
L., A. |
|
Tert. butyl alcohol |
Trichlorethylene |
82.55 |
86.95 |
75 |
16 |
L. |
|
Allyl alcohol |
Carbon tetrachloride |
96.95 |
76.75 |
72.32 |
11.5 |
L. |
|
Allyl alcohol |
Trichlorethylene |
96.95 |
86.95 |
80.95 |
16 |
L. |
|
Allyl alcohol |
Dichloro-bromo-methane |
96.95 |
90.2 |
85.85 |
17.5 |
L. |
|
Allyl alcohol |
Isobutyl bromide |
96.95 |
91.6 |
83.9 |
18 |
L. |
|
Allyl alcohol |
Tetrachlorethylene |
96.95 |
120.8 |
94 |
49 |
L. |
|
Propyl alcohol |
Isobutyl chloride |
97.2 |
68.9 |
67.2 |
7 |
L. |
|
Propyl alcohol |
Propyl bromide |
97.2 |
71.0 |
69.2 |
9 |
B., L. |
|
Propyl alcohol |
Ethyl iodide |
97.2 |
72.3 |
70.1 |
7.8 |
Ry., L. |
|
Propyl alcohol |
Carbon tetrachloride |
97.2 |
76.75 |
72.8 |
11.5 |
B., L. |
|
Propyl alcohol |
Trichlorethylene |
97.2 |
86.95 |
81.75 |
17 |
L. |
|
Propyl alcohol |
Dichloro-bromo-methane |
97.2 |
90.2 |
86.4 |
19.5 |
L. |
|
Propyl alcohol |
Allyl iodide |
97.2 |
102 |
90.0 |
29 |
L. |
|
Propyl alcohol |
Propyl iodide |
97.2 |
102.4 |
90.2 |
30 |
L. |
|
Propyl alcohol |
Tetrachlorethylene |
97.2 |
120.8 |
94 |
54 |
L. |
|
Isobutyl alcohol |
Carbon tetrachloride |
108.0 |
76.75 |
75.8 |
5.5 |
L. |
|
Isobutyl alcohol |
Trichlorethylene |
108.0 |
86.95 |
85.4 |
9 |
L. |
|
Isobutyl alcohol |
Dichloro-bromo-methane |
108.0 |
90.2 |
89.3 |
11 |
L. |
|
Isobutyl alcohol |
Propyl iodide |
108.0 |
102.4 |
96 |
18 |
L. |
|
Isobutyl alcohol |
Isoamyl bromide |
108.0 |
120.2 |
103.8 |
41 |
B., L. |
|
Isobutyl alcohol |
Tetrachlorethylene |
108.0 |
120.8 |
103.05 |
40 |
L. |
|
Isobutyl alcohol |
Ethylene bromide |
108.0 |
1315 |
106.2 |
60.5 |
Ry., L. |
|
Isobutyl alcohol |
Chlorobenzene |
108.0 |
131.8 |
107.2 |
63 |
L. |
|
Isoamyl alcohol |
Isoamyl bromide |
131.8 |
120.2 |
116.4 |
20 |
B., L. |
|
Isoamyl alcohol |
Tetrachlorethylene |
131.8 |
120.8 |
116.0 |
19 |
L. |
|
Isoamyl alcohol |
Ethylene bromide |
131.8 |
131.5 |
123.2 |
90 |
Ry., L. |
|
Isoamyl alcohol |
Chlorobenzene |
131.8 |
131.8 |
124.3 |
36 |
L. |
|
Cyclo-hexanol |
Bromobenzene |
160.65 |
15615 |
153.6 |
33.5 |
L. |
|
Cyclo-hexanol |
Pentachlorethane |
160.65 |
161.95 |
157.9 |
36 |
L. |
|
Methyl alcohol |
Ethyl formate |
64.7 |
54.15 |
50.95 |
16 |
L. |
|
Methyl alcohol |
Methyl acetate |
64.7 |
57.0 |
54.0 |
19 |
Ry., B., L. |
|
Ethyl alcohol |
Ethyl acetate |
78.3 |
77.15 |
71.8 |
30.98 |
W., M. |
|
Ethyl alcohol |
Methyl propionate |
78.3 |
79.7 |
73.2 |
52 |
L. |
|
Isopropyl alcohol |
Ethyl acetate |
82.45 |
77.05 |
74.8 |
23 |
Ry., L. |
|
Substances in mixture. |
Boiling points. |
Percentage of A. by weight in mixture. |
Observer. |
|||
|
A. |
B. |
A. |
B. |
Az. mixture. |
||
|
o |
o |
0 |
||||
|
Propyl alcohol |
Ethyl propionate |
97.2 |
99.1 |
93.4 |
51 |
L. |
|
n. Butyl alcohol |
Methyl isovalerate |
116.9 |
116.3 |
113 |
33 |
L. |
|
Isoamyl alcohol |
Isoamyl acetate |
131.8 |
138.8 |
131.3 |
95 |
H., L. |
|
Ethyl alcohol |
Methyl ethyl ketone |
78.3 |
79.6 |
74.8 |
40 |
Ma., L. |
|
Tert. butyl alcohol |
Methyl ethyl ketone |
82.55 |
79.6 |
78.9 |
- |
A., L. |
|
Isopropyl alcohol |
Methyl ethyl ketone |
82.45 |
79.6 |
77.3 |
30 |
A., L. |
|
Propyl alcohol |
Diethyl ketone |
97.2 |
102.2 |
94.9 |
57 |
L. |
|
Isobutyl alcohol |
Diethyl ketone |
108.0 |
102.2 |
101.95 |
22 |
L. |
|
Octyl alcohol |
Aniline |
178.7 |
184.35 |
177.8 |
65 |
L. |
|
Allyl alcohol |
Epichlorhydrin |
96.95 |
116.4 |
95.8 |
78 |
L. |
|
Propyl alcohol |
Epichlorhydrin |
97.2 |
116.4 |
96.0 |
77 |
L. |
|
Isobutyl alcohol |
Epichlorhydrin |
108.0 |
116.4 |
105.0 |
60.5 |
L. |
|
Isoamyl alcohol |
Epichlorhydrin |
131.8 |
116.4 |
115.35 |
19 |
L. |
|
Allyl alcohol |
Nitromethane |
96.95 |
101.2 |
89 |
60 |
L. |
|
Propyl alcohol |
Nitromethane |
97.2 |
101.2 |
89.15 |
56 |
L. |
|
Benzyl alcohol |
Nitrobenzene |
205.5 |
210.85 |
204.3 |
58 |
L. |
|
Borneol |
Nitrobenzene |
211.8 |
210.85 |
207.75 |
46 |
L. |
|
Methyl alcohol |
Carbon disulphide |
64.7 |
46.2 |
37.65 |
14 |
Ry., Go., L., A. |
|
Ethyl alcohol |
Carbon disulphide |
78.3 |
46.2 |
42.4 |
9 |
Be., Ry., L. |
|
Isopropyl alcohol |
Carbon disulphide |
82.45 |
46.2 |
44.6 |
8 |
Ry., L. |
|
Methyl alcohol |
Acetonitrile |
64.7 |
81.6 |
63.45 |
81 |
V. & D., I. |
|
Ethyl alcohol |
Acetonitrile |
78.3 |
81.6 |
72.5 |
56 |
V. & D., L. |
|
Isopropyl alcohol |
Acetonitrile |
82.5 |
81.6 |
75 |
55 |
L. |
|
Methyl alcohol |
Methylal |
64.7 |
42.2 |
41.82 |
18.2 |
L. |
|
Chlorotoluene |
181.5 |
161.3 |
160.3 |
8 |
L. |
|
|
Phenol |
Pentachlorethane |
181.5 |
161.95 |
160.85 |
9.5 |
L. |
|
Phenol |
Bromotoluene, o. |
181.5 |
181.75 |
174.35 |
40 |
L. |
|
Phenol |
Bromotoluene, p. |
181.5 |
185 |
176.2 |
44 |
L. |
|
Phenol |
Iodobenzene |
181.5 |
188.55 |
177.7 |
47 |
L. |
|
Cresol, o. |
Bromotoluene, o. |
190.8 |
181.75 |
180.3 |
16 |
L. |
|
Cresol, o. |
Bromotoluene, p. |
190.8 |
185 |
181.7 |
25 ' |
L. |
|
Cresol, o. |
Iodobenzene |
190.8 |
188.55 |
185.0 |
32 |
L. |
|
Propionic acid |
Water |
140.7 |
100 |
99.98 |
17.7 |
L. |
|
Isobutyric acid |
Water |
154.35 |
100 |
99.3 |
21 |
L. |
|
Butyric acid |
Water |
163.5 |
100 |
99.4 |
18.4 |
L. |
|
Acetic acid |
Benzene |
118.5 |
80.2 |
80.05 |
2 |
Ne. |
|
Acetic acid |
Toluene |
118.5 |
110.7 |
105.4 |
28 |
Ry., L. |
|
Acetic acid |
Ethyl benzene |
118.5 |
136.15 |
114.65 |
66 |
L. |
|
Acetic acid |
Xylene, m. |
118.5 |
139 |
115.38 |
72.5 |
Ry., L. |
|
Propionic acid |
Ethyl benzene |
140.7 |
13615 |
131.1 |
28 |
L. |
|
Propionic acid |
Xylene, p. |
140.7 |
138.2 |
132.0 |
36 |
L. |
|
Propionic acid |
Xylene, m. |
140.7 |
1390 |
132.65 |
35.5 |
L. |
|
Propionic acid |
Pinene |
140.7 |
155.8 |
136.15 |
58.5 |
L. |
|
Isobutyric acid |
Pinene |
154.35 |
155.8 |
146.7 |
35 |
L. |
|
Isobutyric acid |
Carvene |
154.35 |
177.8 |
151.0 |
78 |
L. |
|
Butyric acid |
Pinene |
163.5 |
155.8 |
152.0 |
25 |
L. |
|
Butyric acid |
Carvene |
163.5 |
177.8 |
160.75 |
55 |
L. |
|
Isovaleric acid |
Carvene |
176.5 |
177.8 |
168.9 |
41 |
L. |
|
Chloracetic acid |
Carvene |
186.5 |
177.8 |
167.8 |
34 |
L. |
|
Acetic acid |
Isobutyl iodide |
118.5 |
120.0 |
107 |
34 |
L. |
|
Acetic acid |
Tetrachlorethylene |
118.5 |
120.8 |
107.35 |
38.5 |
L. |
|
Acetic acid |
Ethylene bromide |
118.5 |
131.5 |
114.35 |
55 |
B. |
|
Acetic acid |
Chlorobenzene |
118.5 |
131.8 |
114.65 |
58.5 |
L. |
|
Propionic acid |
Tetrachlorethylene |
140.7 |
120.8 |
118.95 |
8.5 |
L. |
|
Propionic acid |
Ethylene bromide |
140.7 |
131.5 |
127.75 |
17.5 |
L. |
|
Propionic acid |
Chlorobenzene |
140.7 |
131.8 |
128.75 |
18 |
L. |
|
Propionic acid |
Bromobenzene |
140.7 |
156.15 |
139.85 |
60 |
L. |
|
Isobutyric acid |
Tetrachlorethane, s. |
154.35 |
146.25 |
144.8 |
7 |
L. |
|
Isobutyric acid |
Bromobenzene |
154.35 |
156.15 |
148.6 |
35 |
L. |
|
Isobutyric acid |
Pentachlorethane |
154.35 |
161.95 |
152.9 |
43 |
L. |
|
Butyric acid |
Bromoform |
163.5 |
148.3 |
146 |
7 |
L. |
|
Butyric acid |
Bromobenzene |
163.5 |
15615 |
152.2 |
18 |
L. |
|
Butyric acid |
Chlorotoluene, p. |
163.5 |
161.3 |
156l.3 |
27 |
L. |
|
Butyric acid |
Pentachlorethane |
163.5 |
161.95 |
156.75 |
26 |
L. |
|
Isovaleric acid |
Bromotoluene, o. |
176.5 |
181.75 |
172.1 |
39.5 |
L. |
|
Chloracetic acid |
Benzyl chloride |
186.5 |
179.35 |
172 |
28 |
L. |
|
Chloracetic acid |
Bromotoluene, o. |
186.5 |
181.75 |
172.95 |
32 |
L. |
|
Chloracetic acid |
Bromotoluene, p. |
186.5 |
185.2 |
174 |
47 |
L. |
|
Chloracetic acid |
Iodobenzene |
186.5 |
188.55 |
175.3 |
35 |
L. |
|
Benzene |
n. Hexane |
80.2 |
68.95 |
68.87 |
19 |
J. & Y. |
|
Benzene |
Cyclo-hexane |
80.2 |
80.75 |
77.5 |
55 |
L. |
|
Benzene |
Cyclo-hexene |
80.2 |
82.75 |
79.45 |
85 |
L. |
|
Substances in mixture. |
Boiling points. |
Percentage of A. by weight in mixture. |
Observer. |
|||
|
A. |
B. |
A. |
B. |
Az. mixture. |
||
|
n. Heptane |
Methyl cyclo-hexane |
98.45 |
101.8 |
<98 |
>80 |
L. |
|
Cyclo-hexane |
Cyclo-hexadiene, 1.3 |
80.75 |
80.8 |
79.2 |
52 |
L. |
|
Pinene |
Mesitylene |
163.8 |
164.0 |
162.7 |
52 |
L. |
|
Isopentane |
Ethyl bromide |
27.95 |
38.38 |
23.5 |
70 |
L. |
|
Trimethyl ethylene |
Ethyl bromide |
37.15 |
38.38 |
35.2 |
40 |
L. |
|
n. Hexane |
Chloroform |
68.95 |
61.2 |
59.95 |
28 |
L. |
|
n. Hexane |
Isobutyl chloride |
68.95 |
68.85 |
66.3 |
45 |
L. |
|
n. Hexane |
Propyl bromide |
68.95 |
71.0 |
67.5 |
67 |
L. |
|
n. Hexane |
Ethyl iodide |
68.95 |
72.3 |
68 |
34(?) |
L. |
|
Benzene |
Carbon tetrachloride |
80.2 |
76.75 |
76.75 |
4.4 |
Y. & F., Li., Z., Ro. |
|
Ethyl benzene |
Propylene dibromide |
136.15 |
141.7 |
135.95 |
95 |
L. |
|
Xylene, p. |
Propylene dibromide |
138.2 |
141.7 |
137.5 |
78 |
L. |
|
Xylene, m. |
Propylene dibromide |
139 0 |
141.7 |
138 |
70 |
L. |
|
Pinene, a |
Bromobenzene |
155.8 |
156.1 |
153.4 |
50 |
L. |
|
Carvene |
Benzyl chloride |
177.8 |
179.35 |
174.8 |
54 |
L. |
|
Carvene |
Bromotoluene, o. |
177.8 |
181.75 |
177.3 |
83 |
L. |
|
Isopentane |
Methyl formate |
27.95 |
31.9 |
17.05 |
53 |
L. |
|
n. Pentane |
Methyl formate |
36.15 |
31.9 |
21.8 |
47 |
L. |
|
Trimethylethylene |
Methyl formate |
37.15 |
31.9 |
24.3 |
46 |
L. |
|
Xylene, m. |
Isoamyl acetate |
139.0 |
138.8 |
136 |
50 |
L. |
|
Xylene, m. |
Methyl lactate |
139.0 |
144.8 |
134 |
70 |
L. |
|
Pinene, a |
Ethyl lactate |
155.8 |
155 |
147 |
49 |
L. |
|
Pinene, a |
Methyl oxalate |
155.8 |
163.3 |
144.1 |
61 |
L. |
|
Mesitylene |
Methyl oxalate |
164 |
163.3 |
154.8 |
50.2 |
L. |
|
Carvene |
Methyl oxalate |
177.8 |
163.3 |
156.7 |
25 |
L. |
|
Carvene |
Propyl lactate |
177.8 |
171.7 |
166.35 |
37 |
L. |
|
Carvene |
Isobutyl lactate |
177.8 |
182.15 |
172.5 |
60 |
L. |
|
Carvene |
Ethyl oxalate |
177.8 |
185.0 |
172.2 |
59 |
L. |
|
Ethyl bromide |
Methyl formate |
38.4 |
31.9 |
29.85 |
36 |
L. |
|
Ethyl iodide |
Ethyl acetate |
72.3 |
77.05 |
70.5 |
75 |
Ry., K., Z., Ro„ L. |
|
Carbon tetrachloride |
Ethyl acetate |
76.75 |
77.05 |
74.75 |
57 |
Y. Z., Ty., L. |
|
Carbon terachloride |
Methyl propionate |
76.75 |
79.7 |
75.5 |
60 |
L. |
|
Allyl iodide |
Ethyl propionate |
102 |
99.1 |
97.8 |
40 |
L. |
|
Ally1 iodide |
Propyl acetate |
102 |
101.55 |
99.6 |
50 |
L |
|
Isobutyl iodide |
Isoamyl formate |
120 |
123.6 |
117.5 |
70 |
L. |
|
Tetrachlorethylene |
Ethyl butyrate |
120.8 |
119.9 |
118.4 |
62 |
L. |
|
Tetrachlorethylene |
Ethyl carbonate |
120.8 |
126.0 |
118.55 |
74 |
L. |
|
Chlorobenzene |
Isobutyl propionate |
131.8 |
136.9 |
131.2 |
76 |
L. |
|
Bromobenzene |
Ethyl lactate |
156.1 |
154.5 |
153 |
47 |
L. |
|
Bromobenzene |
Methyl oxalate |
1561 |
163.3 |
153.05 |
72 |
L. |
|
Chlorotoluene, o. |
Ethyl lactate |
159 |
154.5 |
153..5 |
35 |
L. |
|
Chlorotoluene, p. |
Methyl oxalate |
161.3 |
163.3 |
157.0 |
60 |
L. |
|
Pentachlorethane |
Methyl oxalate |
161.95 |
163.3 |
157.55 |
68 |
L. |
|
Benzyl chloride |
Propyl lactate |
179.35 |
171.7 |
171.2 |
22 |
L. |
|
Benzyl chloride |
Isobutyl lactate |
179.35 |
182.15 |
178 |
70 |
L. |
|
Bromotoluene, o. |
Isobutyl lactate |
181.75 |
182.15 |
180 |
56 |
L. |
|
Bromotoluene, o. |
Ethyl oxalate |
181.75 |
185.0 |
177.35 |
60 |
L. |
|
Bromotoluene, p. |
Ethyl oxalate |
185 |
185.0 |
180.4 |
47.3 |
L. |
|
Iodobenzene |
Ethyl oxalate |
188.55 |
185.0 |
181.1 |
40 |
L. |
|
Ethyl ether |
Methyl formate |
34.6 |
31.9 |
28.25 |
44 |
L. |
|
Methyl propyl ether |
Methyl formate |
38.9 |
31.9 |
30.5 |
20 |
L. |
|
Acetal |
Isobutyl formate |
104.5 |
98.3 |
97 |
20 |
L. |
|
Anisol |
Ethyl lactate |
153.85 |
155 |
150.0 |
44 |
L. |
|
Anisol |
Isobutyl butyrate |
153.85 |
157 |
151 |
67 |
L. |
|
Phenetol |
Methyl oxalate |
171.5 |
163.3 |
161.25 |
30 |
L. |
|
Phenetol |
Propyl lactate |
171.5 |
171.7 |
167.l0 |
50 |
L. |
|
Amylmethylal |
Ethyl benzoate |
207.5 |
213 |
206-1 |
85 |
L. |
|
Anisol |
Pinene, a |
153.85 |
155.8 |
150.45 |
56 |
L. |
|
Phenol |
Pinene, a |
181.5 |
155.8 |
152.75 |
19 |
L. |
|
Phenol |
Carvene |
181.5 |
177.8 |
169 |
40.5 |
L. |
|
Cresol, o. |
Carvene |
190.8 |
177.8 |
175.35 |
25 |
L. |
|
Pinene, a |
Dichlorhydrin, a |
155.8 |
174.5 |
152 |
85 |
L. |
|
Carvene |
Dichlorhydrin, a |
177.8 |
174.5 |
165.75 |
57 |
L. |
|
Carvene |
Dichlorhydrin, B |
177.8 |
183 |
169.3 |
40 |
L. |
|
Carvene |
Benzaldehyde |
177.8 |
179.2 |
171.2 |
57 |
L. |
|
Pinene, a |
Aniline |
155.8 |
184.35 |
155.25 |
85 |
L. |
|
Carvene |
Aniline |
177.8 |
184.35 |
171.35 |
61.2 |
L. |
|
Carvene |
Methyl aniline |
177.8 |
196.1 |
174.5 |
87 |
L. |
|
Benzene |
Methyl ethyl ketone |
80.2 |
79.6 |
78.35 |
62.5 |
Ma., L. |
|
Pinene, a |
Methyl acetoacetate |
155.8 |
169.5 |
150.5 |
64 |
L. |
|
Substances in mixture. |
Boiling points. |
Percentage of A. by weight in mixture. |
Observer. |
|||
|
A. |
B. |
A. |
B. |
Az. mix-ture. |
||
|
Pinene, a |
Ethyl acetoacetate |
155.8 |
180.7 |
153.35 |
78 |
L. |
|
Carvene |
Ethyl acetoacetate |
177.8 |
180.7 |
169.05 |
57 |
L. |
|
Terpinene |
Ethyl acetoacetate |
181 |
180.7 |
171 |
51 |
L. |
|
Xylene, p. |
Ethyl chloracetate |
138.2 |
143.5 |
137.0 |
72 |
L. |
|
Xylene, m. |
Ethyl chloracetate |
139.0 |
143.5 |
137.25 |
68 |
L. |
|
Carvene |
Ethyl bromisobutyrate, a |
177.8 |
178 |
174 |
45 |
L. |
|
Toluene |
Epichlorhydrin, a |
110.7 |
116.45 |
108.25 |
74 |
L. |
|
Pinene, a |
Chloracetal |
155.8 |
156.8 |
151 |
55 |
L. |
|
Naphthalene |
Chlorophenol, p. |
218.1 |
217 |
215.9 |
36.5 |
L. |
|
n. Pentane |
Ethyl hydrogen sulphide |
36.15 |
36.2 |
32 |
50 |
L. |
|
Trimethylethylene |
Ethyl hydrogen sulphide |
3715 |
36.2 |
32.95 |
ho |
L. |
|
n. Pentane |
Carbon disulphide |
36.15 |
46.25 |
35.5 |
85 |
L. |
|
Trimethylethylene |
Carbon disulphide |
37.15 |
46.25 |
36.5 |
83 |
L. |
|
n. Pentane |
Ethyl ether |
36.15 |
34.6 |
33.4 |
30 |
L. |
|
Trimethylethylene |
Methylal |
37.15 |
42.25 |
35.3 |
27 |
L. |
|
Toluene |
Stannic chloride |
110.7 |
113.85 |
109.15 |
48 |
L. |
|
Tetrachlorethylene |
Paraldehyde |
120.8 |
124 |
118.75 |
68 |
T. |
|
Benzylchloride |
Benzaldehyde |
179.35 |
179.2 |
177.9 |
50 |
L. |
|
Bromotoluene, o. |
Aniline |
181.75 |
184.35 |
178.65 |
63 |
L. |
|
Bromotoluene, p. |
Aniline |
185 |
184.35 |
180.3 |
40 |
L. |
|
Iodobenzene |
Dimethyl aniline |
188.55 |
194.05 |
187 |
85 |
L. |
|
Isobutyl chloride |
68.9 |
56.25 |
55.8 |
27 |
L. |
|
|
Ethyl iodide |
Acetone |
72.3 |
56.25 |
560 |
20 |
Ry., L. |
|
Carbon tetrachloride |
Acetone |
76.75 |
56.25 |
55.8 |
... |
Hy., A. |
|
Carbon tetrachloride |
Methyl ethyl ketone |
76.75 |
79.6 |
73.8 |
71 |
L., A. |
|
Allyl iodide |
Diethyl ketone |
102 |
102.2 |
100.8 |
66 |
L. |
|
Allyl iodide |
Methyl propyl ketone |
102 |
102.25 |
100.9 |
66 |
L. |
|
Iodobenzene |
Ethyl acetoacetate |
188.55 |
180.7 |
178.0 |
52 |
L. |
|
Isobutyl iodide |
Epichlorhydrin, a |
120 |
116.45 |
110 |
53 |
L. |
|
Tetrachlorethylene |
Epichlorhydrin, a |
120.8 |
116.45 |
110.12 |
48.5 |
L. |
|
Isopropyl chloride |
Carbon disulphide |
36.25 |
46.25 |
36.0 |
78 |
L. |
|
Ethyl bromide |
Carbon disulphide |
38.4 |
46.25 |
37.85 |
67 |
Ry., L. |
|
Methyl iodide |
Carbon disulphide |
42.6 |
46.25 |
41.65 |
59 |
L. |
|
Propyl chloride |
Carbon disulphide |
46.6 |
46.25 |
45.2 |
45 |
L. |
|
Ethylidene chloride |
Carbon disulphide |
57.3 |
46.25 |
46 |
6 |
L. |
|
Dichloromethane |
Methylal |
41.5 |
42.2 |
39 |
62 |
L. |
|
Methyl iodide |
Methylal |
42.6 |
42.2 |
39.35 |
57 |
L. |
|
Benzyl chloride |
Cineol |
179.35 |
176.3 |
175.5 |
19 |
L. |
|
Ethylene dibromide |
Chlorobenzene |
131.5 |
131.8 |
129.75 |
55 |
L. |
|
Carbon disulphide |
Acetone |
46.25 |
56.25 |
39.25 |
66 |
Ry., Y., Ro„ M., L. L. |
|
Carbon disulphide |
Methyl ethyl ketone |
46.25 |
79.6 |
45.85 |
84.7 |
|
|
Carbon disulphide |
Methyl formate |
46.25 |
31.9 |
24.75 |
33 |
L. |
|
Carbon disulphide |
Ethyl formate |
46.25 |
54.15 |
39.35 |
63 |
L. |
|
Carbon disulphide |
Methyl acetate |
46.25 |
57.0 |
40.15 |
70 |
L. |
|
Carbon disulphide |
Ethyl acetate |
46.25 |
77.05 |
46.1 |
97 |
L. |
|
Carbon disulphide |
Ethyl ether |
46.25 |
34.6 |
34.5 |
1 |
Gu., Ry., Y., L. |
|
Carbon disulphide |
Methyl propyl ether |
46.25 |
38.8 |
36.2 |
18 |
L. |
|
Carbon disulphide |
Methylal |
46.25 |
42.25 |
37.25 |
46 |
Z.,Y. |
|
Acetone |
Diethylamine |
56.1 |
55.5 |
51.35 |
38.2 |
Ma., L. |
|
Diethyl ketone |
Nitromethane |
102.2 |
101.2 |
99.1 |
45 |
L. |
|
Methyl propyl ketone |
Nitromethane |
102.25 |
101.2 |
99.15 |
44 |
L. |
|
Acetone |
Methyl acetate |
56.25 |
57.0 |
56.1 |
55 |
Ry., L. |
|
Methyl ethyl ketone |
Methyl propionate |
79.6 |
79.7 |
79.25 |
52 |
L. |
|
Methyl ethyl ketone |
Propyl formate |
79.6 |
80.8 |
79.45 |
55 |
L. |
|
Diethyl ketone |
Propyl acetate |
102.2 |
101.55 |
101.35 |
ho |
L. |
|
Methyl propyl ketone |
Propyl acetate |
102.25 |
101.55 |
101.35 |
38 |
L. |
|
Ethyl chloracetate |
Methyl lactate |
143.5 |
144.8 |
140.4 |
52 |
L. |
|
Isoamyl chloracetate |
Ethyl oxalate |
190.5 |
185.0 |
181.5 |
35 |
L. |
|
Methyl ethyl ketone |
Water |
79.57 |
100.0 |
73.57 |
88.6 |
M., L. |
|
Pyridine |
Water |
115.5 |
100.0 |
92.6 |
57 |
Gd., L. |
Continue to:
liquids, distillation, vapour, boiling point, composition, still-head, mixtures, compositions, sublimation, alcohol, acetone, water, purification, pressure, tar, raw material, essential oils
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