Rust And Corrosion

Iron is easily corroded by even the weak acids. Sulphuric acid, nitric acid, and hydrochloric acid all act on it quickly and powerfully. Air and moisture also quickly corrode it. It is a curious fact that carbonate of soda protects iron very perfectly from rust. We have seen a piece of iron that had been kept in a solution of soda for twenty years, and yet was quite bright.

There are several methods of protecting iron from rust. Painting, varnishing, tinning, zincing, etc., have all been tried with good effect. Painting and varnishing need no remarks. Where bright work is to be temporarily protected, however, a paint of white lead and tallow may be used. This will not dry, and may be easily and quickly removed with a little turpentine.

Zincing Iron

The following is an excellent and cheap method for protecting from rust, iron articles exposed to the atmosphere, such as cramp-irons for stone, etc.: They are to be first cleansed by placing them in open wooden vessels, in water containing three-fourths to one per cent, of common sulphuric acid, and allowed to remain in it until the surface appears clean, or may be rendered so by scouring with a rag or wet sand. According to the amount of acid, this may require from six to twenty-four hours. Fresh acid must be added according to the extent of use and of the liquid; when this is saturated with sulphate of iron, it must be renewed. After removal from this bath, the articles are rinsed in fresh water, and scoured until they acquire a clean metallic surface, and then kept in water in which a little slaked lime has been stirred, until the next operation. When thus freed from rust, they are to be coated with a thin film of zinc, while cold, by means of chloride of zinc, which may be made by filling a glazed earthen vessel, of about two-thirds gallon capacity, three-fourths full of muriatic acid, and adding zinc clippings until effervescence ceases. The liquid is then to be turned off from the undissolved zinc, and preserved in a glass vessel. For use, it is poured into a sheet-zinc vessel, of suitable size and shape for the objects, and about l.30 per cent, of its weight of finely powdered sal ammoniac added. The articles are then immersed in it, a scum of fine bubbles forming on the surface in from one to two minutes, indicative of the completion of the operation. The articles are next drained, so that the excess may flow back into the vessel. The iron articles thus coated with a fine film of zinc are placed on clean sheet iron, heated from beneath, and perfectly dried, and then dipped piece by piece, by means of tongs, into very hot (though not glowing) molten zinc, for a short time, until they acquire the temperature of the zinc. They are then removed and beaten, to cause the excess of zinc to fall off.

Cold Process For Zincing Iron

The metal is first cleaned by being placed in a bath made up of water, 1,000 litres; chlorhydric acid, 550 litres; sulphuric acid, 50 litres; glycerine, 20 litres. On being removed from this bath, the metal is placed in a bath containing 10 per cent, of carbonate of potassa, and is next transferred to a metallizing bath, consisting of water, 1,000 litres; chloride of tin, 5 kilos.; chloride of zinc, 4 kilos.; bitartrate of potassa, 8 kilos.; acid sulphate of alumina, 4 kilos.; chloride of aluminum, 10 kilos. The metal is to be left in this mixture for from three to twelve hours, according to the thickness of the layer of zinc to be desired.