This section is from the "Henley's Twentieth Century Formulas Recipes Processes" encyclopedia, by Norman W. Henley and others.
Instead of nitric acid, which has a tendency to lift up the etching-ground, by evolution of gases, it is better to use a mixture of potassium bichromate, 150 parts; water, 800 parts; and concentrated sulphuric acid, 200 parts. The etching is slow, but even, and there is no odor.
Pure nitric acid diluted with water to 18° Bé. The bubbles of gas given out should immediately be removed with a feather that the etching may be even.
Another compound consists of a boiling solution of potassium chlorate, 2 parts, in water, 20 parts, poured into a mixture of nitric acid, 10 parts, and water, 70 parts. For delicate etchings dilute still more with 100 to 200 parts of water.
Weak: A boiling solution of potassium chlorate, 20 parts, in water, 200 parts, poured into a mixture of pure hydrochloric acid, 20 parts; water, 500 parts.
Stronger: A boiling solution of potassium chlorate, 25 parts, in water, 250 arts, poured into a mixture of pure hydrochloric acid, 250 parts; water, 400 parts.
Very strong: A boiling solution of potassium chlorate, 30 parts, in water, 300 parts, poured into a mixture of pure hydrochloric acid, 300 parts; water, 300 parts.
For etching on copper a saturated solution of bromine in dilute hydrochloric acid may also be used; or a mixture of potassium bichromate, 0.5 part; water, 1 part; crude nitric acid, 3 parts.
The following are also much used for copper and copper alloys:
A copper chloride solution acidified with hydrochloric acid.
Copper nitrate dissolved in water.
A ferric chloride solution of 30° to 45° Bé. If chrome gelatin or chrome albumen is used for the etching-ground, a spirituous ferric chloride solution is employed. The etching process can be made slower by adding common salt to the ferric chloride solution.
White vitriol, 1 to 5 parts; common salt, 1 part; concentrated sulphuric acid, 100 parts; nitric acid (36° Bé.), 200 parts, mixed together. The sulphuric acid is to be poured carefully into the nitric acid, not the reverse.
Nitric acid, 8 parts; mixed with water, 80 parts; into this mixture pour a hot solution of potassium chlorate, 3 parts, in water, 50 parts.
Mix nitric acid, of 1.3 specific weight, with enough fuming nitric acid to give a deep yellow color. This mixture acts violently, and will eat through the strongest sheet brass.
 
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