Chloride of methyl was discovered in 1840 by Messrs. Dumas and Peligot, who obtained it by treating methylic alcohol with a mixture of sea salt and sulphuric acid. It is a gaseous product at ordinary temperature, but when compressed and cooled, easily liquefies and produces a colorless, neutral liquid which enters into ebullition at 237.7° above zero and under a pressure of 0.76 m.

VINCENTS ICE MACHINE. FIG. 1.  THE FREEZER (Longitudinal Section).

VINCENTS ICE MACHINE. FIG. 1.--THE FREEZER (Longitudinal Section).

Up to recent times, chloride of methyl in a free state had received scarcely any industrial application, by reason of the difficulty of preparing it in a state of purity at a low price. Mr. C. Vincent, however, has made known a process which permits of this product being obtained abundantly and cheaply. It consists in submitting to the action of heat the hydrochlorate of trimethylamine, which is obtained as a by-product in the manufacture of potash of beets. The hydrochlorate is thus decomposed into free trimethylamine, ammonia, and chloride of methyl. A washing with hydrochloric acid takes away all traces of alkali, and the gas, which is gathered under a receiver full of water, may afterward be dried by means of sulphuric acid, and be liquefied by pressure.

VINCENTS ICE MACHINE. FIG. 2.  THE FREEZER (Transverse Section).

VINCENTS ICE MACHINE. FIG. 2.--THE FREEZER (Transverse Section).

Pure liquid chloride of methyl is now an abundant product. There are two uses to which it is applied: first, for producing cold, and second, for manufacturing coal tar colors.

VINCENTS ICE MACHINE. FIG. 3.  HALF PLAN OF FREEZER

VINCENTS ICE MACHINE. FIG. 3.--HALF PLAN OF FREEZER

At present we shall occupy ourselves with the first of such applications--the production of cold.

The apparatus serving for the production of cold by this material are three in number: (1) the freezer (Figs. 1, 2, and 3), in which is produced the lowering of temperature that converts into ice the water placed in carafes or any other receptacles; (2) the pump (Figs. 4, 5, and 6), which sucks the chloride of methyl in a gaseous state up into the freezer and forces it into the liquefier; and (3) the liquefier, which is nothing else than a spiral condenser in which the chloride of methyl condenses, and from thence returns to the freezer to serve anew for the production of cold.

VINCENTS ICE MACHINE. FIG. 4.  THE PUMP (Longitudinal Section).

VINCENTS ICE MACHINE. FIG. 4.--THE PUMP (Longitudinal Section).