Description Of The Francke "Tina" Or Vat Process For The Amalgamation Of Silver Ores.

By Mr. EDGAR P. RATHBONE, of London.

In the year 1882, while on a visit to some of the great silver mines in Bolivia, an opportunity was afforded the writer of inspecting a new and successful process for the treatment of silver ores, the invention of Herr Francke, a German gentleman long resident in Bolivia, whose acquaintance the writer had also the pleasure of making. After many years of tedious working devoted to experiments bearing on the metallurgical treatment of rich but refractory silver ores, the inventor has successfully introduced the process of which it is proposed in this paper to give a description, and which has, by its satisfactory working, entirely eclipsed all other plans hitherto tried in Bolivia, Peru, and Chili. The Francke "tina" process is based on the same metallurgical principles as the system described by Alonzo Barba in 1640, and also on those introduced into the States in more recent times under the name of the Washoe process.[2]

It was only after a long and careful study of these two processes, and by making close observations and experiments on other plans, which had up to that time been tried with more or less success in Bolivia, Peru, and Chili - such as the Mexican amalgamation process, technically known as the "patio" process; the improved Freiberg barrel amalgamation process; as used at Copiapo; and the "Kronke" process - that Herr Francke eventually succeeded in devising his new process, and by its means treating economically the rich but refractory silver ores, such as those found at the celebrated Huanchaca and Guadalupe mines in Potosi, Bolivia. In this description of the process the writer will endeavor to enter into every possible detail having a practical bearing on the final results; and with this view he commences with the actual separation of the ores at the mines.

Ore Dressing, Etc

This consists simply in the separation of the ore by hand at the mines into different qualities, by women and boys with small hammers, the process being that known as "cobbing" in Cornwall. The object of this separation is twofold: first to separate the rich parts from the poor as they come together in the same lump of ore, otherwise rich pieces might go undetected; and, secondly, to reduce the whole body of ore coming from the mine to such convenient size as permits of its being fed directly into the stamps battery. The reason for this separation not being effected by those mechanical appliances so common in most ore dressing establishments, such as stone breakers or crushing rolls, is simply because the ores are so rich in silver, and frequently of such a brittle nature, that any undue pulverization would certainly result in a great loss of silver, as a large amount would be carried away in the form of fine dust. So much attention is indeed required in this department that it is found requisite to institute strict superintendence in the sorting or cobbing sheds, in order to prevent as far as practicable any improper diminution of the ores.

According to the above method, the ores coming from the mine are classified into the four following divisions:

1. Very rich ore, averaging about six per cent. of silver, or containing say 2,000 ounces of silver to the ton (of 2,000 lb.).

2. Rich ore, averaging about one per cent. of silver, or say from 300 to 400 ounces of silver to the ton.

3. Ordinary ore, averaging about ½ per cent. of silver, or say from 150 oz. to 200 oz. of silver to the ton.

4. Gangue, or waste rock, thrown on the dump heaps.

The first of these qualities - the very rich ore - is so valuable as to render advantageous its direct export in the raw state to the coast for shipment to Europe. The cost of fuel in Bolivia forms so considerable a charge in smelting operations, that the cost of freight to Europe on very rich silver ores works out at a relatively insignificant figure, when compared with the cost of smelting operations in that country. This rich ore is consequently selected very carefully, and packed up in tough rawhide bags, so as to make small compact parcels some 18 in. to 2 ft. long, and 8 in. to 12 in. thick, each containing about 1 cwt. Two of such bags form a mule load, slung across the animal's back.

The second and third qualities of ore are taken direct to the smelting works; and where these are situated at some distance from the mines, as at Huanchaca and Guadalupe, the transport is effected by means of strong but lightly built iron carts, specially constructed to meet the heavy wear and tear consequent upon the rough mountain roads. These two classes of ores are either treated separately, or mixed together in such proportion as is found by experience to be most suitable for the smelting process.

On its arrival at the reduction works the ore is taken direct to the stamp mill. At the Huanchaca works there are sixty-five heads of stamps, each head weighing about 500 lb., with five heads in each battery, and crushing about 50 cwt. per head per twenty-four hours. The ore is stamped dry, without water, requiring no coffers; this is a decided advantage as regards first cost, owing to the great weight of the coffers, from 2 to 3 tons - a very heavy item when the cost of transport from Europe at about 50l. per ton is considered. As fast as the ore is stamped, it is shoveled out by hand, and thrown upon inclined sieves of forty holes per lineal inch; the stuff which will not pass through the mesh is returned to the stamps.

Dry stamping may be said to be almost a necessity in dealing with these rich silver ores, as with the employment of water there is a great loss of silver, owing to the finer particles being carried away in suspension, and thus getting mixed with the slimes, from which it is exceedingly difficult to recover them, especially in those remote regions where the cost of maintaining large ore-dressing establishments is very heavy. Dry stamping, however, presents many serious drawbacks, some of which could probably be eliminated if they received proper attention. For instance, the very fine dust, which rises in a dense cloud during the operation of stamping, not only settles down on all parts of the machinery, interfering with its proper working, so that some part of the battery is nearly always stopped for repairs, but is also the cause of serious inconvenience to the workmen. At the Huanchaca mines, owing to the presence of galena or sulphide of lead in the ores, this fine dust is of such an injurious character as not unfrequently to cause the death of the workmen; as a precautionary measure they are accustomed to stuff cotton wool into their nostrils.