In addition to ethyl alcohol, whisky has acids, alcohols higher than ethyl (butyl, propyl, amyl, etc.) esters (ethers), aldehydes, furfurols and numerous compounds thereof. These are produced during fermentation (congeneric with ethyl alcohol) or are formed during ageing. Whisky also contains extractives from the wood (usually oak) in which it is aged. These extractives are tannin, acid and coloring matters. To these congeneric and synthesized bodies and extracts from the wood, whisky owes its flavor and aroma (organoleptic properties). For this reason whiskies which have long aged in wood are most highly esteemed and regarded as least harmful. Following is a table showing the chemical composition of some common whiskies.

Approximate Composition of Whiskies of Different Kinds

Parts per 100,000 of proof alcohol

Kind of whisky

Proof

Nonvolatile matter

Acidity as acetic acid

Esters

Aldehydes

Furfural

Higher alcohols

Total congeneric and secondary products

Old Rye.................................

110

180

80

70

12

2.3

165

300

Old Bourbon....................

105

160

70

55

10

2.0

140

270

New Rye....................

100

8

9

30

5

1.0

135

174

New Bourbon.................

100

8

10

30

3

0.5

130

170

Rye Bottled in Bond...................................

100

190

90

75

18

2.0

150

335

Bourbon Bottled in Bond....................................

100

170

74

60

25

1.5

125

275

Whisky Bottled in Bond....................................

100

180

80

65

18

1.5

150

300

1 Distillery Bottled......

80

650

80

45

12

1.4

115

250

1 Bottled Bourbon......

85

480

45

24

7

1.5

85

150

1 Bottled Rye..............

88

575

48

28

6

1.3

70

140

1 Bottled Whisky......

85

600

55

34

8

1.3

75

150

1 Bulk Whiskies..............

80

450

40

15

4

1.0

50

100

1 Neutral Spirits..........

190

00

1

15

0

0.0

5

25

The above table gives a fair average expression of the chemical constituents of different kinds of whiskies found upon the market. The remarkable chemical differences in new and old whiskies are shown by a comparison of the new Rye whisky and Bourbon whisky with old Rye and old Bourbon whisky. The principal difference, as is seen, is in the amount of extractive material, or solid matter. The extractive matter in old whiskies comes chiefly from the wood.