Zinc coatings on the surface of galvanized iron pipe are attacked and dissolved by some waters almost as energetically as is lead pipe. Zinc is also dissolved to a considerable extent from brass pipes. At Cwmfelin,* in Wales, galvanized iron pipe that conducts water from a spring to the town, a distance of one-half mile, was found to change the character of the water as shown by the following analysis:

At Spring none

At Delivery

114

Nitrogen as nitrates.....

.8

none

Total residue .... . .

154.3

270

Zinc carbonate .... ...

none

91.6

Table XVII - Lead In Samples Of Surface Waters, Arranged According To Average Amount Of Lead Found When Water Is In Ordinary Use

(parts per 100,000 - .05 part per 100,000, Dangerous.)

LOCALITY

SAMPLES TAKEN

Lead

(Average)

Average Length of Pipe (Feet)

Average

Size of Pipe (Inches)

Free

C. 0.2

Hardness

Lawrence. . . .

In ordinary use

.0543

104

3/4

1.100

1.6

After standing in pipe . .

.0704

Weymouth . . .

In ordinary use

.0314

109

3/4

0.152

0.3

After standing in pipe . .

.1167

Metropolitan supply -

In ordinary use

.0111

85

3/4

1.105

1.3

After standing in pipe . .

.0293

Andover . . .

In ordinary use

.0108

122

3/4

0.119

1.0

After standing in pipe . .

.0257

Beverly ....

In ordinary use

.0087

84

3/4

0.121

2.3

After standing in pipe . .

.0147

Cambridge . . .

In ordinary use

.0025

58

3/4

1.225

2.7

After standing in pipe . .

.0064

(Report Massachusetts State Board of Health, 1900, page 491.)

The effect on ground and surface waters that are conducted through galvanized iron and brass service pipes can be judged from the results in Tables XIX, XX, XXI and XXII.

To briefly sum up, it may be stated that it is always better to determine experimentally the action of water upon pipes than to try and predict it from a knowledge of the character of the water. It is better still to only use pipes that are not affected to any appreciable extent by the solvent action of any water. If, however, pipes must be used that are so affected, then those should be selected, the dissolved metals of which are the least injurious to the human system.

The necessity of using pipes that are not injurious is manifest, when it is considered that a water which is perfectly wholesome and non-solvent may be changed at any time for a different supply that might energetically

Table XIX - Zinc In Samples Of Ground Water. (Parts Per 100,000 )

LOCALITY

SAMPLES TAKEN

Zinc (Average)

Average

Length of Pipe

(Feet)

Average

Size of Pipe

(Inches)

West Berlin . . . .

In ordinary use

1.8469

Galv. Iron 4.000

. .

After standing in pipe . . .

Millbury. . . . . .

In ordinary use

.3084

, 53

3/4

After standing in pipe . . .

.7931

Newton. . . . .

In ordinary use

.1254

74

3/4

After standing in pipe . . .

.5551

Marblehead . . . .

In ordinary use

.0857

65

5/8

After standing in pipe . . .

.4914

Grafton. . . . .

In ordinary use

.0733

117 Brass

3/4

After standing in pipe . . .

.3257

Lowell (cook and hy- draulic wells) . .

In ordinary use

.....

40

3/4

After standing in pipe . . .

.2867

Wellesley. . . . . .

In ordinary use

.0686

60

3/4

After standing in pipe . . .

.2257

Fairhaven . . . .

In ordinary use.....

.0527

-

. .

After standing in pipe . . .

.6686

Lowell (boulevard .

wells)

In ordinary use

.0338

90

1 1/8

After standing in pipe . . .

.1522

Webster. . . . .

In ordinary use

.0286

100

1/2

After standing in pipe . . .

.3628

Reading. . . .

In ordinary use

.0000

40

. .

After standing in pipe . . .

.0000

Warren. . . .

In ordinary use

.0000

Galv. Iron Cistern

. .

After standing in pipe . . .

.0000

(Report Massachusetts State Board of Health, 1900, page 495.) attack the pipes, or, the character of the water itself might change sufficiently to dissolve the metal.

Copper is also dissolved from brass pipes, as may be seen from the following tables of analysis of ground and surface waters drawn from brass service pipes.

Table XX - Zinc In Samples Of Surface Water. (Parts Per 100,000.)

LOCALITY

SAMPLES TAKEN

Zinc (Average)

Average

Length of Pipe

(Feet)

Average

Size of Pipe

(Inches)

Sheffield. . . . . .

In ordinary use.....

.8657

Galv. Iron 246

3/4

After standing in pipe . . .

........

Palmer. . . . . . .

In ordinary use ......

.2900

. .

• •

After standing in pipe . . .

.4280

Beverly. . . . . .

In ordinary use . . .

.2714

1,128

2

After standing in pipe . . .

.......

Fall River . . . .

In ordinary use.....

.0070

49

Brass

92

5/8

After standing in pipe . . .

.0103

Metropolitan supply .

In ordinary use.....

.0000

1

After standing in pipe . . .

.0000

(Report Massachusetts State Board of Health, 1900, page 495)

The effect of some water upon different metals of which water pipes are made or coated, and the resultant effect upon the health of those drinking the waters are shown in Table XXIII.

Table XXI - Copper In Samples Of Ground Water (Parts Per 100,000.)

LOCALITY

SAMPLES TAKEN

Copper (Average)

Average

Length of Brass Pipe

(Feet)

Average

Size of Pipe

(Inches)

Wellesley . . . .

In ordinary use.....

.0257

60

3/4

After standing in pipe . . '.

.0286

Lowell (boulevard wells).....

In ordinary use

.0076

90

1 1/8

After standing in pipe . . .

.0233

Lowell (cook and hy- draulic wells . . .

In ordinary use . . . .

40

3/4

After standing in pipe . . .

.0000

Table XXII - Copper In Samples Of Surface Water (Parts Per 100,000.)

LOCALITY

SAMPLES TAKEN

Copper (Average)

Average

Length of Brass Pipe

(Feet)

Average

Size of Pipe

(Inches)

Malden

In ordinary use.....

.0000

20

3/8

After standing in pipe . . .

.0470

Metropolitan supply .

In ordinary use.....

.0050

92

1

After standing in pipe . . .

.0000

Lawrence . . . .

In ordinary use

0000

10

3/4

After standing in pipe . . .

.0000

Wakefield . . . .

In ordinary use.....

6

1/2

After standing in pipe . . .

.0000

Table XXIII - Effect Of Metals On Health

Kind of Pipe

Action of Water

Effect upon People

Lead pipe.....

Dissolves lead

Dangerous

Tin or tin lined lead

No effect

No effect

Galvanized iron ....

Dissolves zinc

Injurious

Tin lined iron.....

No effect

No effect

Brass pipe ....

Slightly dissolves copper and zinc

Objectionable

* Plain iron ....

Rusts and dissolves

Objectionable

Aluminium

No effect

No effect

Nickel.....

No effect

No effect

Benedict nickel ....

No effect

No effect

The action of water upon galvanized iron pipes is almost as energetic as upon lead pipes, and under suitable conditions will dissolve equal amounts of metal from each. However, the effect of the zinc upon the health is not dangerous but only injurious, because zinc is not a cumulative poison, and so long as the initial dose is not sufficient to cause illness or death, the effect is soon thrown off without apparent injury. Lead, on the contrary, even when taken in small doses, remains in the system until sufficient poison accumulates to cause serious illness or death, or if the initial dose is of sufficient strength the effect may be immediately fatal.

* Dissolved iron or rust in small quantities is not injurious to health, but 1/4 grain of iron per gallon of water imparts an objectionable taste to the water besides making it unfit for washing and for most manufacturing purposes.

Lead pipes are more extensively used than any other kind of pipes for water supply in buildings. Sheet lead also is extensively used for lining water tanks. Within the past few years, however, a rational decrease in the use of lead supply pipes and lead lined tanks is noticeable. Galvanized iron pipes, which are cheaper and better in every way, are fast supplanting lead pipes, and when perfect security from metal poisoning is desired, Benedict nickel seamless tubing, tin-lined lead, or tin-lined iron pipes may be used. From a hygienic standpoint, Benedict nickel and tin-lined pipes are about equal, but when superior finish is desired the Benedict nickel tubing will be found the more satisfactory. In appearance it is equal to nickel-plated brass pipe, and in all other respects superior to it.