This section is from the book "Fermented Alcoholic Beverages, Malt Liquors, Wine, And Cider", by C. A. Crampton. Also available from Amazon: Fermented Beverage Production, Second Edition.
The object of this operation is the germination of the grain, and the consequent formation of the ferment diastase, which shall subsequently, under the proper conditions, perform its specific function of converting the starchy portions of the grain into saccharine or fermentable matter. Barley is the grain used almost exclusively for this purpose, its advantages having been recognized even by the Egyptians; they seem to be principally of a physical character, consisting of the firmness of the kernel, and the hard husk, which freely allows the entrance of water, but prevents the passage of starch or insoluble matter.
The operations through which the grain is successively passed are called, technically, steeping, crushing, flooring, and kiln-drying. In the first it is spread out in large vats, covered with water, and allowed to steep several days. When it has become softened, the water is run off and the swollen grain is subjected to a slight degree of heat, which causes it to germinate. This is the second operation. The operation of flooring has for its end the regulation of the germination of the grain, and the time when it has progressed sufficiently is judged by the length which has been attained by the acrospire or plumule. This is variously given as from two-thirds to seven-eighths the length of the grain. The sprouted grain is now spread out in the malt kilns and heat applied, while a current of air circulates about it. After the moisture is driven off, which is done at a low temperature, about 90° F., the heat is raised, and finished at from 125° to 180° F., according to the grade of malt required, the difference between pale, amber, and brown malt being due simply to the temperature at which they are kiln-dried. This last operation serves not only to drive off the moisture, but also stops germination by destroying the vitality of the germ, and fits it for keeping. It also probably develops the flavor by the formation of a minute quantity of empyreumatic oil in the husk.
The rootlets and germs are removed in this process by the turning and stirring of the grain. The water which is used in the process of steeping the grain is an important factor in the production of good malt, and the preference of brewers for hard lime waters for this purpose has been shown by recent experiment to be rational, for it is found that when barley is steeped with distilled water, a very putrescible liquor is obtained charged with albuminous matter, while if a hard water is used these matters remain in an insoluble condition in the grain.
Chemically considered a good malt should not contain more than 5 per cent, of water, and the soluble extract should constitute about 70 per cent, of the weight of the malt and should have a good diastatic action on starch mucilage. The determination of the acidity is important in determining the keeping qualities of the beer which is to be brewed from it, and should not be over .3 per cent, (calculated as lactic).
The following analyses by O'Sullivan show the composition of pale malt:
(1) | (2) | |
Starch....................... .......................... | 44.15 | 45.13 |
Other carbohydrates (of which 60-70 per cent, consist of fermentable sugars). Inulin (?) and a small quantity of other bodies soluble in cold water..........__ | 21.23 | 19.39 |
Cellulose matter........................................ | 11.57 | 10.09 |
Fat..................................................... | 1.65 | 1.96 |
Albuminoids | 13.09 | 13.80 |
Ash................................................... | 2.60 | 1.92 |
Water | 5.83 | 7.47 |
100.12 | 99.76 |
 
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