This section is from the book "A Text-Book Of Pharmacology, Therapeutics And Materia Medica", by T. Lauder Brunton. Also available from Amazon: A text-book of pharmacology, therapeutics and materia medica.
Sources. - Its chief source is copper pyrites, which is a double sulphide of copper and iron.
General Reactions. - Ammonia throws down a pale blue precipitate of hydrate, which is soluble in excess, forming a deep blue solution. Potassium ferrocyanide gives a maroon red precipitate.
Prepared from | By | |
Copper, B.P. . | Copper pyrites | Roasting with sand and coal. |
Copper sulphate, B. and U.S.P. | Copper ........... | Heating copper or its oxide with sulphuric acid, dissolving in water and crystallising. |
Copper nitrate, B.P. | Ditto | Dissolving in nitric acid, evaporating and crystallising. |
Copper acetate, B. and U.S.P. | Copper sulphate | Precipitating with acetate of lead. |
General Impurity. - Iron.
General Test. - If an aqueous solution of a copper salt be mixed with twice its volume of chlorine water, any iron present is converted into a ferric salt. If solution of ammonia be now added, cupric hydrate will fall as a precipitate of a pale blue colour, but is redissolved by excess, forming a deep blue solution. If iron be present, it will be precipitated by the ammonia and not redissolved.
Cuprum, Cu = 63.4. B.P. Copper. - Fine copper wire, about No. 25 wire gauge, or 0.02 inch.
Use. - To detect the presence of metals, as silver, mercury, and arsenic, by their being precipitated on its surface and forming a stain. It is employed in the preparation of sulphate and nitrate of copper and of spirit of nitrous ether.
 
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