Brightening Pickle

To brighten articles by dipping, the dipping liquid must not be too hot, otherwise the pickled surface turns dull; neither must it be prepared too thin, nor must wet articles be entered, else only tarnished surfaces will be obtained.

For a burnish-dip any aqua fortis over 33° Bé., i. e., possessing a specific gravity of 1.30, may be employed. It is advisable not to use highly concentrated aqua fortis, to reduce the danger of obtaining matt work. It is important that the quantity of oil of vitriol, which is added, is correct. It is added because the action of the aqua fortis is very uncertain. Within a short time it becomes so heated in acting on the metals that it turns out only dull work, and pores or even holes are apt to be the result of the violent chemical action. If the aqua fortis is diluted with water the articles do not become bright, but tarnish. For this reason sulphuric acid should be used. This does not attack the metals; it only dilutes the aqua fortis and distributes the heat generated in pickling over a larger space. It is also much cheaper, and it absorbs water from the aqua fortis and, therefore, keeps it in a concentrated state and yet distributed over the space.

In the case of too much oil of vitriol the dilution becomes too great and the goods are tarnished; if too little is added, the mixture soon ceases to turn out bright articles, because of overheating. On this experience are based the formulas given below.

Dip the articles, which must be free from grease, into the pickle, after they have been either annealed and quenched in diluted sulphuric acid or washed out with benzine. Leave them in the dipping mixture until they become covered with a greenish froth. Then quickly immerse them in a vessel containing plenty of water, and wash them out well with running water. Before entering the dipped articles in the baths it is well to remove all traces of acid, by passing them through a weak soda or potassium cyanide solution and washing them out again. If the brightly dipped goods are to remain bright they must be coated with a thin spirit or zapon acquer.

Following are two formulas for the pickle:

I

Aquafortis, 36°Bé., by weight....... 100 parts

Oil of vitriol (sulphuric acid), 66° Bé., by weight .. 70 parts

Cooking salt, by volume......... 1.5 parts

Shining soot (lampblack), by volume ........... 1.5 parts

II

Aqua fortis, 40° Bé., by weight....... 100 parts

Oil of vitriol, 66° Be., by weight .. . 100 parts

Cooking salt, by volume......... 2 parts

Shining soot, by volume......... 2 parts