List Of Known Azeotropic Mixtures. Part 2
Description
This section is from the book "Distillation Principles And Processes", by Sydney Young. Also available from Amazon: Distillation Principles And Processes.
List Of Known Azeotropic Mixtures. Part 2
Table 13. Binary Azeotropic Mixtures - Maximum Boiling Point
Substances in mixture. | Percentage of A. by weight in mixture. | |||||
Observer. | ||||||
A. | B. | A. | B. | Az mix ture. | ||
Water | Nitric acid | 100.0 | 86.0 | 120.5 | 32 | R. |
Water | Hydrochloric acid | 100.0 | -84 | 110 | 79.76 | R. |
Water | Hydrobromic acid | 100.0 | -73 | 126 | 52.5 | R |
Water | Hydriodic acid | 100.0 | -34 | 127 | 43 | R. |
Water | Hydrofluoric acid | 100.0 | 19.4 | 120 | 63 | R. |
Water | Formic acid | 100.0 | 99.9 | 107.1 | 22.5 | R. |
Water | Formic acid | 100.0 | 100.75 | 107.3 | 22.5 | L. |
Water | Perchloric acid | 100.0 | 110.0 | 203 | 28.4 | R. |
Formic acid | Diethyl ketone | 100.75 | 102.2 | 105.4 | 33 | L. |
Formic acid | Methyl propyl ketone | 100.75 | 102.25 | 105.3 | 32 | L. |
Propionic acid | Acetylacetone | 140.7 | 138 | 144 | 70 | L. |
Hydrochloric acid | Methyl ether | - 84 | -23.65 | -1.5 | 60 | F., L. |
Formic acid | Pyridine | 100.7 | 116.7 | 149 | 18 | Ga., An., Z„ L. |
Formic acid | Picoline, a | 100.7 | 134 | 158 | 25 | Ga., L. |
Acetic acid | Pyridine | 118.5 | 115.5 | 139.7 | 35 | Ga., An., L. |
Acetic acid | Picoline, a | 118.5 | 134 | 146 | 40 | Ga., Z. |
Propionic acid | Pyridine | 140.7 | 116.7 | 150.151 | 31.5 | Ga., An., L. |
Cyclo-hexanol | 181.5 | 160.65 | 182.45 | 90.5 | L. | |
Phenol | Sec. octyl alcohol | 181.5 | 178.5 | 184.65 | 50 | L. |
Phenol | Glycol | 181.5 | 197.4 | 199 | 22 | L. |
Cresol, p. | Glycol | 201.8 | 197.4 | 203 | 68 | L. |
Cresol, p. | Benzyl alcohol | 201.8 | 205.5 | 207.0 | 38 | L. |
Phenol | Benzaldehyde | 181.5 | 179.2 | 185.6 | 51 | L. |
Phenol | Aniline | 181.5 | 184.35 | 186.22 | 42 | L. |
Cresol, o. | Dimethyl aniline | 190.8 | 194.05 | 195.6 | <30 | L. |
Cresol, o. | Methyl aniline | 190.8 | 196.1 | 196.7 | 10 | L. |
Cresol, p. | Toluidine, p. | 201.8 | 200.3 | 204.35 | 57 | L. |
Cresol, p. | Toluidine, o. | 201.8 | 200.7 | 204.5 | 53 | L. |
Cresol, p. | Ethyl aniline | 201.8 | 206.05 | 207.2 | <20 | L. |
Cresol, o. | Acetophenone | 190.8 | 202 | 203.7 | 22 | L. |
Cresol, p. | Fenchone | 201.8 | 193 | 205 | 72 | L. |
Cresol, p. | Acetophenone | 201.8 | 202 | 208.45 | 50 | L. |
Cresol, p. | Camphor | 201.8 | 208.9 | 213.15 | 30 | L. |
Cresol, m. | Acetophenone | 202.8 | 202 | 209 | 52 | L. |
Cresol, m. | Camphor | 202.8 | 208.9 | 213.5 | 35 | L. |
Phenol | Isoamyl butyrate | 181.5 | 178.6 | 185.6 | 61 | L. |
Phenol | Isobutyl lactate | 181.5 | 182.15 | 189.05 | 46 | L. |
Phenol | Ethyl oxalate | 181.5 | 185 0 | 189.1 | 43 | L. |
Cresol, o. | Ethyl oxalate | 190.8 | 1850 | 193.9 | 67 | L. |
Cresol, o. | Methyl benzoate | 190.8 | 199.55 | 200.8 | 30 | L. |
Cresol, p. | Methyl benzoate | 201.8 | 199.55 | 204.7 | 85 | L. |
Cresol, p. | Isoamyl lactate | 201.8 | 202.4 | 207.25 | 48 | L. |
Cresol, m. | Methyl benzoate | 202.8 | 199.55 | 205.6 | 88 | L. |
Cresol, m. | Isoamyl lactate | 202.8 | 202.4 | 207.6 | 50 | L. |
56.4 | 61.2 | 64.7 | 20 | Ry., Th., L., Ty., Y. | ||
Diethyl ketone | Dichloro-bromo-methane | 102.2 | 90.2 | 103.0 | 64 | L. |
Camphor | Benzal chloride | 208.9 | 205.1 | 209.7 | 75 | L. |
Chloroform | Ethyl formate | 61.2 | 54.15 | 62.7 | 87 | L. |
Chloroform | Methyl acetate | 61.2 | 57.05 | 64.8 | 77 | Ry., L. |
Pentachlorethane | Mesitylene | 161.95 | 164.0 | 166 | 44 | L. |
Hydrogen bromide | Hydrogen sulphide | . . . | . . . | -70 | 61 | S. &B. |
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