This section is from the book "Mechanics Of The Household", by E. S. Keene. Also available from Amazon: Mechanics Of The Household.
Acetylene is a gas that is generated when water is absorbed by calcium carbide, after the manner in which carbonic acid gas is evolved when lime slakes with water, but with the liberation of a larger amount of the combustible gas.
Calcium carbide is a product resulting from the union of lime and coke, fused in an electric furnace to form a grayish-brown mass. It is brittle and more or less crystalline in structure and looks much like stone. It will not burn except when heated with oxygen. A cubic foot of the crushed calcium carbide weighs 160 pounds.
Calcium carbide - or carbide as it is ordinarily termed - may be preserved for any length of time if kept sealed from the air, but the ordinary moisture of the atmosphere gradually slakes it and after exposure for a considerable time it changes into slaked lime. The carbide itself has no odor, but in the air it is always attended by the penetrating odor of acetylene, because of the gas liberated by the moisture absorbed from the air.
If protected from moisture, calcium carbide cannot take fire, being like lime in this respect; it is therefore a safe substance to store. It is transported under the same classification as hardware, and will keep indefinitely if properly sealed.
A pound of pure carbide yields 5 1/2 cubic feet of acetylene, but in commercial form, as rated by the National Board of Fire Underwriters, lump carbide is estimated at 4 1/2 cubic feet per pound. In the generation of acetylene, exact weights of carbide and water always enter into combination, i.e., 64 parts of carbide to 34 parts of water, and a definite amount of heat is evolved for each part of carbide consumed.
Uncontrolled, the gas burns with a bright but not brilliant flame and with a great deal of smoke, but when used in a burner suited for its combustion it burns with a clear brilliant flame of a quality approaching sunlight. While carbide is not explosive nor inflammable, it may, if it finds access to water, create a pressure such as to burst its container, and it is not impossible that heat might be generated sufficient to ignite the gas under such conditions. That such condition would often occur is not at all probable. When water is sprinkled upon carbide, in quantity such that it will all be taken up, the resultant slaked lime is left dry and dusty, and occupies more space than the original carbide. When more than enough water is employed, the remaining mixture of lime and water is whitewash.
Chemically considered, acetylene is C2H2; it is composed of carbon and hydrogen and belongs to a class of compounds known as hydrocarbons, represented in nature by petroleum, natural gas, etc. It is composed of 92.3 per cent. carbon and 7.7 per cent. of hydrogen, both combustible gases. It is a non-poisonous, colorless gas, with a persistent and penetrating odor. Its presence in the air, to the extent of 1 part in 1000 is distinctly perceptible. When burning brightly in a jet, there is no perceptible odor. When completely burned it requires for its combustion 2 1/2 times its volume of oxygen.
All combustible gases, when mixed with air and ignited, produce more or less violent explosions. Acetylene is no exception to the rule, and when allowed to escape into any enclosed space it will quickly produce a violently explosive mixture, so that it is always dangerous to enter a room or basement with a lamp or flame of any kind where the odor of gas is perceptible. This is quite true with a combustible gas of any kind, but with acetylene all mixtures from 3 to 30 per cent. are capable of being exploded with greater or less violence.
The kindling point of acetylene is lower than coal gas or gasoline gas. To ignite either of the latter gases, a flame is necessary to start the combustion, but a spark or a glowing cigar is sufficient to ignite acetylene. It should therefore be borne in mind that acetylene is not only explosive when mixed with air but that it is very easy to ignite. Under ordinary pressures pure acetylene is not explosive, but at pressure above 15 pounds to the square inch explosions sometimes occur where proper precautions are not observed. At all pressures such as are required for household purposes acetylene is as safe for use as any other gas.
Although acetylene is in danger of exploding when under pressure, it is perfectly safe, when the proper conditions are observed, in tanks for a great many kinds of portable lights.
Where acetylene is used in portable tanks under pressure, advantage is taken of its solubility in acetone. This is a product of the distillation of wood which possesses the property of absorbing acetylene to a remarkable degree. In addition to this property is the more important one of rendering the acetylene non-explosive when under pressure. The tanks for its storage are filled with asbestos or other absorbent material that is saturated with acetone. The acetylene is then forced into the tanks under pressure and is absorbed by the acetone. The safety of this means of storage lies in the degree of perfection to which the tanks are filled with the absorbent material. There must be no space anywhere in the tank where undissolved acetylene can exist. Its freedom from danger under such conditions has been thoroughly demonstrated in its use for railroad and automobile lamps.
The use of acetylene as a fuel for cooking and for the various other purposes of domestic use is successfully accomplished in burners that give the blue flame desired for such purposes. Complete cooking ranges and various other heating and cooking devices are regularly sold by dealers in heating appliances, while water-heaters, hot-plates, chafing-dish heaters, etc., are as much a possibility as with any other of gaseous fuel and in as reasonably an inexpensive way.
Coal gas, containing as it does sufficient carbon monoxide to render it poisonous, will cause death when inhaled for any length of time, but acetylene under the same conditions will have no deleterious effect.
 
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