This section is from the book "Fermented Alcoholic Beverages, Malt Liquors, Wine, And Cider", by C. A. Crampton. Also available from Amazon: Fermented Beverage Production, Second Edition.
Especial attention has been given in the present investigation to the use of improper preserving agents in fermented drinks. It was thought that such agents were much used; so a considerable number of samples were purchased, and the examination for preservatives, as well as for other adulterations whose detection did not require a complete analysis of the wine, was extended to all. The results show the practice to be even more extensive than was supposed.
The following table shows in what samples salicylic acid and sulphites were detected. In the case of the sulphites, where a "trace" is indicated, there was not sufficient to justify the assertion that a sulphite or sulphurous acid had been added directly to the wine; in such cases it probably came from insufficient cleansing of the casks. Where it is indicated as "present," however, there was sufficient indication of its having been added to the wine.
Examination of wines for preservatives. | ||||
Designation. | Made in- | Serial number. | Salicylic acid. | Sulphites. |
Champagne | New York | 4960 | None..... | None. |
Do....................................... | do........... | 4961 | ___do____ | Do. |
Do...................................... | Ohio............ | 4962 | ...do____ | Do. |
Do....................................... | 4963 | ...do..... | Present | |
Burgundy | 4961 | ...do____ | None. | |
Virginia seedling | 4965 | ...do..... | Do. | |
Catawba | New York...... | 4966 | Present... | Do. |
Sweet Scuppernong | North Carolina. | 4967 | None___ | Do. |
Charbono | California | 4968 | ...do..... | Do. |
Lenoire | ... do........... | 4969 | ...do .... | Do. |
St.Macaire | ...do........... | 4970 | ...do..... | Do. |
Angelica | do........... | 4994 | ... do____ | Do. |
Burgundy | ...do........... | 4995 | .. do____ | Trace. |
Claret ......................................... | ...do........... | 4996 | ...do.... | None. |
Moselle | ...do........... | 4997 | ...do____ | Present. |
Riesling, Gray | do........... | 4998 | Present.. | None. |
Riesling, Johannisberg | ...do........... | 4999 | ...do.... | Present |
Sauterne | do........... | 5000 | None..... | Do. |
Sherry | ...do........... | 5001 | Present... | None. |
Sweet Burgundy | do | 5002 | None____ | Do. |
Sweet Muscatel | do........... | 5003 | ...do .... | Do. |
Tokay....................................... | ...do.......... | 5004 | ...do . | Do. |
Zinfandel | do........... | 5005 | ...do..... | Do. |
Catawba | 5081 | ...do..... | Trace. | |
California Hock | 5082 | ...do..... | Present. | |
California Riesling | 5083 | ...do. .. | Trace. | |
Burgundy | 5084 | .. do.... | None. | |
Zinfandel | 5085 | ...do..... | Do. | |
St.-Julien Claret | 5086 | ...do..... | Trace. | |
Sweet Catawba................................ | New York...... | 5087 | do..... | None. |
St.-Julien Claret............................... | 5088 | Present .. | Trace. | |
Riesling | 5089 | None..... | Present | |
Sherry........................................ | California...... | 5090 | .. do.... | None. |
Port........................................... | ... do........... | 5091 | .. do___ | Do. |
Muscatel | ... do........... | 5092 | .. do____ | Do. |
Angelica | ... do........... | 5093 | Present... | Do.. |
Claret.......................................... | Virginia....... | 5094 | None | Do. |
Zinfandel | California...... | 5095 | .. do..... | Do... |
Claret ........................................ | Virginia | 5096 | ...do..... | Trace |
Riesling | California...... | 5097 | ...do .. | Present. |
California Berger | .. do........... | 5098 | ...do..... | None. |
Claret........................................ | Virginia....... | 5099 | ... do..... | Do. |
Do......................................... | New Jersey.. | 5100 | Present__ | Do. |
Do......................................... | Virginia........ | 5101 | None | Do. |
Catawba | 5102 | Present... | Do. | |
Claret | California...... | 5103 | None..... | Do. |
Do......................................... | ... do.......... | 5104 | ...do____ | Do. |
Do......................................... | Virginia....... | 5105 | .. do..... | Do. |
Sauterne | 5106 | .. do..... | Present | |
Hock | 5107 | Present... | Do | |
California Beaune | 5108 | .. do.... | None. | |
Sweet Catawba | 5109 | ...do.... | Trace. | |
California Gutedel | 5110 | ...do..... | Present | |
Claret.......................................... | 5111 | None | Do. | |
California Zinfandel | 5112 | -do .___ | Trace. | |
California Port | 5113 | do..... | None | |
Sonoma Port | 5114 | Present... | Do | |
California Angelica | 5115 | do .... | Do. | |
Frontignan | California | 5116 | None | Do. |
Old Pale Sherry................................ | do........... | 5117 | do___ | Do. |
California Zinfandel | 5118 | Present.. | Trace | |
Gutedel Hock | California | 5119 | None____ | Do. |
Berger Hock | ...do........... | 5120 | do | Present. |
California Burgundy | do........... | 5121 | Present | Trace. |
California Madeira | do | 5123 | do | None. |
California Port | do........... | 5124 | None | Do. |
California Tokay | do........... | 5125 | Present | Do |
California Frontignan | ...do........... | 5126 | None | Do. |
California Angelica | do | 5127 | do..... | Do. |
California Berger Hock | do | 5128 | do..... | Present |
From an examination of this table it will be seen that of the seventy samples examined, eighteen, or over one-fourth, had received an addition of salicylic acid, and thirteen had been preserved by the use of sulphurous acid, either as such, or in the shape of a sulphite. In two cases both agents had been used. One of the samples which contained salicylic acid and also one containing sulphites were among the samples exhibited at the meeting of the National Viticultural Convention last year in Washington.
The question of the propriety of the use of preservatives has been very fully discussed in previous pages, and will not be further enlarged upon here.
Baumert found no salicylic acid in the samples examined by him, and only traces of sulphurous acid.
The examination of the samples for boracic acid gave such peculiar results that I hesitate about pronouncing positively upon them until I shall have had opportunity to investigate the matter more closely. The test with turmeric paper gave slight traces present in all but two of the thirty-six samples which were submitted to a complete analysis. With only a very few, however, could any test be obtained with the alcohol flame. Baumert obtained the same test in everyone of the samples he examined. He seeks to account for this by the fact that plants have been known to assimilate boracic acid from the soil, and knowing that in some parts of California the soil contains considerable quantities of borax, he offers it as an explanation that it was taken up by the vine from the soil. This explanation seems hardly tenable, and in view of the fact that some of the samples I examined came from various parts of the country other than California, must be thrown aside as insufficient. It is a singular fact that both of the samples in which I failed to get the test, Nos. 5087 and 5102 were Catawba wines.
I can offer no explanation of the matter except the suspicion, which I hope to be able to investigate, that the trouble lies with the test.
 
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